Volume Change Accompanied with Sol-Gel transition of fish meat sol.

Flow birefringence at the sol-gel transition

2014 The information provided by a flow birefringence experiment at the sol-gel transition in the sol phase is discussed There are two competing effects : cluster rotations, and cluster elastic deformation. In a steady state, rotational effects turn out to be dominant. For small velocity gradients S we predict an extinction angle x such that 03C0/4 x diverges with an exponent roughly equal to 3...

Viscoelastic Properties for Sol-Gel Transition

Two Simple Approaches to Sol-Gel Transition

We represent a theory of polymer gelation as an analogue of liquid-glass transition in which elastic fields of stress and strain shear components appear spontaneously as a consequence of the cross-linking of macromolecules. This circumstance is explained on the basis of obvious combinatoric arguments as well as a synergetic Lorenz system, where the strain acts as an order parameter, a conjugate...

Entropic Elasticity at the Sol-Gel Transition

The sol-gel transition is studied in two purely entropic models consisting of hard spheres in continuous three-dimensional space, with a fraction p of nearest neighbor spheres tethered by inextensible bonds. When all the tethers are present (p = 1) the two systems have connectivities of simple cubic and face-centered cubic lattices. For all p above the percolation threshold pc, the elasticity h...

Molecular Dynamics approach of sol–gel transition: Comparison with experiments

A new aggregation model by a Molecular Dynamics approach at constant temperature was compared with experimental results on a zirconia precursor gelling process. The evolution of the distribution of the experimental scattered intensities (small angle X-ray scattering curves), during gelling, was compared with the results of our Molecular Dynamics method, via the computation of structure factors ...